The technological potential of PV
The basics of PV systems
The fundamental element of any PV system is the PV cell. A PV cell
is a particular semiconductor device that is able to convert sunlight directly
into electricity (direct current). PV cells are inherently low voltage,
high-current density devices. Several series-connected cells are needed to from
a module , the basic commercial components of PV systems. Serval modules
are then connected to from a string. The in series and/or in parallel connection
of different strings makes it possible to obtain practically any desired
operating voltage for the final PV system.
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How PV cells work
The possibility of producing electrical energy directly from
sunlight is based on some properties of semiconductor materials, and
particularly on the interaction occurring in certain solid materials between
photons (light packets or "quanta") and the electrons of the solid-state atomic
matrix.
Semiconductors are characterized by the existence of a so-called
"energy band gap." This is the finite difference between the energy level of
electrons in a stable position in the crystal structure - the valence band - and
the next allowed electron energy band level, known as the conduction
band, in which an electron can move freely through the material. The
magnitude of the gap is different for each semiconductor material.
In an equilibrium situation at room temperature with no external
applied fields, the semiconductor valence band is completely filled by the
valence (external orbital) electrons, whereas the conduction band is completely
free of electrons. When the semiconductor is exposed to sunlight, photons with
an energy content higher than the band gap can excite electrons from their
stable energy level (the valence band) to higher energy levels (the conduction
band), leaving a so-called hole in the valence band. In this state, if an
external electric field is applied, the material is able to carry electricity.
However, in order to produce electricity, a further step is
needed. In the absence of an electric field, the excited electrons in the
conduction band will recombine with the holes. That is, they will "relax" into
the vacant, lower energy levels in the valence band, and no current will be
observed. In effect, the electrons excited by the photons need to be oriented by
an electric field to produce useful current. The basic concept of a PV device is
to produce this electric field internally in the solid. This is achieved
by combining semiconductor materials with different characteristics to form a
junction. Two configurations, namely homojunctions and heterojunctions, are
possible. In homojunctions, two differently doped layers of the same
semiconductor are combined, whereas heterojunctions are made by two (or more)
semiconductors with different energy gaps.
In the junction zone a built-in electric field is
established, which is able spatially to separate the photo-excited electrons
from the holes and start them drifting in opposite directions. If the cell
material quality is good enough, the carriers will reach the external electric
contacts of the cell and a voltage between the latter will be observed
(photovoltaic effect). If an external load is applied, direct current will pass
through the electric circuit. The PV cell is then generating useful electrical
power.
PV cells are inherently low-voltage, high-current-density devices.
A typical commercial crystalline silicon cell (10 cm x 10 cm area) can produce a
current of up to 3 amperes at a voltage of only 0.5 volts. Several
series-connected cells are therefore needed to form a module, the basic
commercial component of PV systems. A commercial silicon module (0.4
m2 area) produces between 40 Wp and 50 Wp at
17V voltage. Several modules are then connected to form a string. The in series
and/or in parallel connection of different strings makes it possible to obtain
practically any desired operating voltage for the final PV system (from low
voltage for household applications to 20kV for large power plants). are needed
to form a module, the basic commercial component of PV systems. Several modules
are then connected to form a string. The in series and/or in parallel connection
of different strings makes it possible to obtain practically any desired
operating voltage for the final PV system (from low voltage for household
applications to 20kV for large power plants)
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Depending on the type of electrical connection, there are two main
categories of PV systems: the autonomous (stand-alone) and the grid connected
systems.
In the stand-alone systems, the PV field is connected to a means
of energy storage (usually electrical batteries). The energy produced can thus
also be used when the sun does not shine.
In the grid-connected systems, usually no accumulation systems are
employed and the electricity is fed directly into the grid. Power conditioning
systems are needed to operate the system at maximum power and to avoid stability
problems in the electricity network. Finally, an inverter is needed to convert
the direct current produced by the PV modules into useful alternating current.
However, it should be noted that many appliances (e.g. all electronic devices
and several high-efficiency lamps) could run on direct current. Several
companies are exploring the possibility of introducing a dual supply for their
products.
The final part of a PV system is its supporting structure. There
are two categories of system: those mounted on purpose-built structures (i.e.
power plants in open fields and PV systems on flat roofs), and
building-integrated systems, which use part of the building structure for
support.
In current terminology there are two basically different parts to
a PV system: the PV module; and all other structures and means by which the
electricity produced by the module can be delivered to the grid or to the final
users. This so-called "Balance-of-System´' includes all supporting
structures, power conditioning systems, wiring, and eventual energy storage
systems.
PV technologies
There are many different possible technologies for manufacturing
PV cells and modules. A classification can be made with regard to system types,
manufacturing processes' and semiconductor materials. One main distinction can
be made between crystalline semiconductor cells and thin-film devices.
Thanks to the related experience of the electronics industry,
crystalline silicon cells dominate the PV market at present. In 1993 they
had 84 per cent of market share (Vigotti 1994a). Crystalline silicon cells use
scraps from the electronics industry as a feedstock. Today, this mature
technology is the only one that can simultaneously offer high stability, long
lifetimes, high module efficiencies (15.3 per cent for high-purity
monocrystalline Si modules and 11.1 per cent for polycrystalline Si modules of
slightly lower purity), and advanced production status (see also table 7.1).
However, this particular technology will have to give way to other
PV technologies in the near-mid future, for at least two reasons. First, demand
by the PV industry will soon exceed the amount of scrap material offered by the
electronics industry. Second, and more important, the present technology derives
directly from the electronics industry and is not optimized for PV cell
production. The present manufacturing processes of crystalline silicon cells are
very inefficient in terms of the consumption of both primary energy and raw
materials. This is also reflected in the present high cost of PV systems.
In the near future, so-called "solar-grade" crystalline silicon
cells will most likely be used. Solar-grade silicon is much less pure than
electronics-grade silicon, but pure enough for PV cells. Solar-grade silicon
manufacturing processes rely on completely different purification processes of
metallurgical silicon. These processes are much simpler than the ones currently
used for silicon cells derived from electronics scraps. They are also expected
to be much more efficient as far as primary energy consumption and raw materials
use are concerned. Up to 1995, there had been no large-scale production of
solar-grade silicon. However, solar-grade silicon production has top priority on
the agenda of several PV industries, particularly in Europe and in Japan.
In the mid-long term, the large-scale use of thin-film PV devices
is expected. Thin films are based on yet another completely different approach
and manufacturing process from those employed for crystalline PV cells. Whereas
crystalline silicon requires a thickness of about 200 microns to absorb 90 per
cent of incident light, thin films need only a few microns of active material to
collect the same amount of radiation. Consequently, far less semiconductor
material is needed. This greatly decreases costs and reduces primary material
resource use and primary energy consumption during manufacturing. Secondly,
thin-film production techniques are particularly well suited for large scale
production. Thin-film deposition is done by directly spraying or sputtering the
active material onto a glass or metal substrate. This continuous process is far
more efficient than the batch processes of crystalline cell production.
Moreover, it allows a manufacturer to produce cells as large as complete
crystalline modules. This increases the effective active area and eliminates the
problems and costs of connecting a number of cells together to form a module.
Moreover, by stacking several thin-film layers, multifunction cells can be
produced. In such a cell, each layer absorbs a different part of the light
spectrum. In principle, the theoretical efficiency limit of multifunction cells
is much higher than that of conventional cells. Finally, several thin-film
modules are semi-transparent. Therefore, they can be used in buildings as PV
"windows" or PV glazing surfaces.
Table 7.1 Conversion efficiency of venous PV technologies at
the different stages of their development (%)
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Cell type
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Largest standard commercial
modulea
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Best prototype module
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Area (cm2)
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Best laboratory cell
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Area (cm2)
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Theoretical limit
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Production status
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CRYSTALLINE SEMICONDUCTOR
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Silicon
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Monocrystalline Si
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15.3
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20.8
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743
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24.0
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4.00
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30-33
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Large-scale
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19.5
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3,080
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21.6
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47.00
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Polycrystalline Si (p-Si)
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11.1
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17.0
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17.2
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100.00
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22
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Large-scale
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EFG-band p-Si
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14.7
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50.00
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Small-scale
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Dendritic Web
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17.0
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4.00
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Pilot prod.
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GaAs
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Monocrystalline on GaAs
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29.0
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0.05
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Small-scale
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Monocrystalline on other substrate
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17.6
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1.00
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Pilot
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THIN FILMS
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Amorphous silicon (a-Si)
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6.8
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10.2
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933
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12.7
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1.00
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27-28
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Large-scale
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12.0
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100.00
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p-Si on ceramic (100 microns thick)
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11.2
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225
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14.9
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1.00
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20
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Polycrystalline silicon
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15.7
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1.00
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Polycrystalline GaAs
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8.8
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8.00
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CdTe
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7.25
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10.0
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15.8
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1.00
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28
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Pilot
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7.7
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3,528
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CIS
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11.1
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15.9
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1.00
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23.5
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Pilot
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9.7
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3,880
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13.9
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7.00
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Mechanically stacked a-Si and CIS
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15.6
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4.00
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42
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GaAsb
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22.0
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29.3
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0.50
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GaAs on GaSbb
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34.0
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37.0
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0.05
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Sources: Green and Emery (1994), Kelly (1993), IAEA (1992),
Proceedings of the 1st PV World Conference (1995).
a. Typical commercial PV
module areas range from 0.5 to 0.75 m2.
b. Concentrator systems:
in these systems direct radiation is concentrated on a small cell by
means of a Fresnel lens.
In table 7.1, the conversion efficiencies1 of the
various PV technologies at the different stages of their development are
summarized. The important thing to note is that efficiencies much higher than
those of commercial modules have been achieved in the laboratory. Thus there is
still considerable potential for further improvement between the theoretical and
commercial limits. Uncertainties regarding production costs, the investments
needed, and the rapidity of technological improvement make it impossible to
select a single best or most likely PV system for the future.
However, it is much more important to realize that all PV
technologies are in rapid evolution. Figure 7.1 shows the past efficiency
evolution over time for different types of cells. Moreover, the fact that
several technology development paths seem capable of providing comparable PV
cell efficiencies and costs in the future means that there is likely to be
competition between different design approaches. In turn, this is likely to
accelerate improvements in PV technology and the industrialization process and
to reduce manufacturing costs.
PV applications
PV systems are highly modular and therefore offer a wide range of
applications. As already mentioned, the series and/or parallel connection of
different modules and/or strings allow one to obtain practically any desired
operating voltage for the final PV system. Figure 7.2 summarizes the
applications of PV systems as a function of installed peak power. As shown, the
range of possible applications extends from very small devices such as solar
calculators or watches to the grid-connected multi-megawatt power plants.

Fig. 7.1 Efficiency evolution over time
per type of PV laboratory cell
Today, PV systems for communications and solar home systems have
the largest market share (21 per cent and 15 per cent respectively) (EPIA 1995).
Up to 2010, the two largest markets expected are (a) solar home systems in
developing countries, and (b) grid connected, mainly building-mounted systems in
industrialized countries (see also the section on "A PV market diffusion
strategy").
PV is very well suited to provide electricity to rural and remote
areas in developing countries. Whereas taking the electricity grid to the people
living in those areas would imply enormous investments and might take decades,
small PV stand-alone solar home systems with a small battery storage are cost
effective and can meet some basic needs such as lighting and TV. This would
tremendously increase the quality of life of the local population. It would also
encourage people to stay in their communities rather than migrate to a
megalopolis in the hopes of increasing their standard of living. Although the
cost of a solar home system today (around US$500) is relatively expensive for
rural conditions, it could be subsidized by low-interest financing programmes.
This is currently being done by the World Bank in some Asian countries.

Fig. 7.2 PV applications
The application of building-integrated PV systems is particularly
interesting, because it shows several advantages compared with "conventional" PV
power plants. First, the occupation of surfaces already used for other purposes
substantially reduces the main environmental obstacle to the adoption and
diffusion of PV, namely land requirements. As a consequence, it greatly
increases the potential applicability of PV in areas of high population density.
Second, integration into already existing or planned supporting structures and
the substitution of building envelope materials reduce total system costs.
Because total energy consumption during the manufacturing and installation of
the systems is reduced, the energy payback time2 of the PV system is
also reduced and its (indirect and low) environmental impacts are further
lowered. Finally, this application actually expands the technological potential
of PV systems, because in buildings they can play more roles than solely
producing electricity. For instance, building-integrated PV panels can save
energy when used as sun shading systems. Moreover, in buildings, there is the
possibility of recovering a significant fraction of the thermal energy
dissipated by the PV panels. This thermal energy can be used directly for room
heating in winter and for pre-heating of water in all seasons. Potentially very
interesting is the coupling of PV building-integrated systems with other
solar-passive, bioclimatic architecture and energy-saving measures. This has
significant environmental implications. Recent Life Cycle Analysis studies show
that already building-integrated PV systems can "avoid" over twice the CO2
emissions compared with conventional PV power plants (Frankl 1994)3.
These environmental benefits will increase with future PV technologies as
conversion efficiencies increase and energy consumption during manufacturing
decreases.
This application is poised to take off right now (1995), because
practically all PV manufacturers worldwide are getting involved in developing
new products to be integrated with buildings. Some non PV cell producers are
specializing in this sector as well, by purchasing cells and selling specific
products for the buildings market. Products range from PV roof-tiles, to
facades, construction materials, and colour modules. Applications range from
office, residential, and industrial buildings up to carpark roofs and highway
sound barriers.
This phenomenon could have enormous implications, because it
raises the number of interested and involved actors by orders of magnitude, on
both the supply and the demand side. The result will be to promote competition
and investment in the PV sector. PV will be a subject of interest not only for
the limited number of PV industries and electricity utilities around the world,
but potentially for millions of architects and engineers, as well as for their
clients.